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Manufacturer
Products description
High temperature resistant, permanently elastic silicone sealant Universal
Capacity ml: 70 ml
Packing Type: Tube
Material: Silicone
chem. Feature: curing
chem. Feature: no solvent-
chem. Feature: Permanently elastic
Temperature range ° C: -50 ° C - +320 ° C ° C
Colour: anthracite
Typical applications:
oil pan
Timing chain housing
valve cover
crankcase
thermostat,
water Pump
transmission
differential
Safety notice:
Page 1/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 31.07.2018 Revision: 17.07.2018Version number 15
SECTION 1: Identification of the substance/mixture and of the company/undertaking
· 1.1 Product identifier
· Trade name: REINZOSIL (200 ml)
· MSDS code: 70-31414-20
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture
Sealant
Silicone sealant
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Reinz-Dichtungs-GmbH
Reinzstr. 3-7
D-89233 Neu-Ulm
Germany
Tel.: +49-(0)731-7046-0
E-Mail: sdb.qus@dana.com
· Further information obtainable from: Department ASU
· 1.4 Emergency telephone number: +49 731 / 7046 - 301
* SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Aerosol 2 H223-H229 Flammable aerosol. Pressurised container: May burst if heated.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms GHS02
· Signal word Warning
· Hazard statements
H223-H229 Flammable aerosol. Pressurised container: May burst if heated.
· Precautionary statements
P102 Keep out of reach of children.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P251 Do not pierce or burn, even after use.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
· Supplemental information:
EUH210 Safety data sheet available on request.
· 2.3 Other hazards No further relevant information available.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
* SECTION 3: Composition/information on ingredients
· 3.2 Chemical characterisation: Mixtures
· Description:
Polydimethylsiloxane with inorganic fillers and oximosilane as curing agent
Packed in: Two-chamber pressure can
Inner chamber (discharge):
Polydimethylsiloxane with inorganic fillers and oximosilane as curing agent (Contd. on page 2)
GB
Page 2/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 31.07.2018 Revision: 17.07.2018Version number 15
Trade name: REINZOSIL (200 ml)
(Contd. of page 1)
47.0.4
Outer chamber:
Propane, butane, isobutane liquid gas mixture according to DIN 51622 as propellant
Active substance with propellant
· Dangerous components:
CAS: 74-98-6
EINECS: 200-827-9
Reg.nr.: 01-2119486944-21-xxxx
propane
Flam. Gas 1, H220; Press. Gas (Comp.), H280
1-<5%
CAS: 58190-62-8
EC number: 700-810-0
Reg.nr.: 01-2120006148-66-xxxx
2-Pentanone, O,O',O''-(ethenylsilylidyne)trioxime
Acute Tox. 4, H302; Eye Irrit. 2, H319
1-<5%
CAS: 106-97-8
EINECS: 203-448-7
Reg.nr.: 01-2119474691-32-xxxx
butane
Flam. Gas 1, H220; Press. Gas (Comp.), H280
1-<5%
CAS: 128446-60-6 3-Aminopropyl(methyl)silsesquioxane, ethoxy-terminated
Flam. Liq. 3, H226; Skin Irrit. 2, H315; Eye Irrit. 2, H319
1-<5%
· SVHC -
· Additional information:
For the wording of the listed hazard phrases refer to section 16.
While curing the following substances are formed and released by a reaction with atmospheric humidity:
CAS: 623-40-5
ELINCS: 484-470-6
Reg.nr.: 01-2119980079-27-xxxx
2-Pentanone oxime
Acute Tox. 4, H302; Eye Irrit. 2, H319; Aquatic Chronic 3, H412
SECTION 4: First aid measures
· 4.1 Description of first aid measures
· General information: Take affected persons out into the fresh air.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Remove from the skin using a cloth or paper. Then clean with water and soap.
If skin irritation continues, consult a doctor.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Information for doctor: No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5: Firefighting measures
· 5.1 Extinguishing media
· Suitable extinguishing agents:
Use fire extinguishing methods suitable to surrounding conditions.
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· 5.2 Special hazards arising from the substance or mixture No further relevant information available.
· 5.3 Advice for firefighters
· Protective equipment: Wear self-contained respiratory protective device.
SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation. (Contd. on page 3)
GB
Page 3/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 31.07.2018 Revision: 17.07.2018Version number 15
Trade name: REINZOSIL (200 ml)
(Contd. of page 2)
47.0.4
· 6.2 Environmental precautions: No special measures required.
· 6.3 Methods and material for containment and cleaning up:
Ensure adequate ventilation.
Pick up mechanically.
Dispose of the material collected according to regulations.
· 6.4 Reference to other sections
By a reaction with atmospheric humidity by-products are released. See chapter 8.
SECTION 7: Handling and storage
· 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.
· Information about fire - and explosion protection: No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Protect from heat and direct sunlight.
· 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
CAS: 106-97-8 butane
WEL Short-term value: 1810 mg/m³, 750 ppm
Long-term value: 1450 mg/m³, 600 ppm
Carc (if more than 0.1% of buta-1.3-diene)
· Additional Occupational Exposure Limit Values for possible hazards during processing:
While curing the following substances are formed and released by a reaction with atmospheric humidity:
2-Pentanonoxime (CAS 623-40-5)
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Avoid contact with the eyes and skin.
Do not inhale gases / fumes / aerosols.
Wash hands before breaks and at the end of work.
Do not eat, drink, smoke or sniff while working.
· Respiratory protection:
Not necessary if room is well-ventilated.
Use suitable respiratory protective device in case of insufficient ventilation.
Filter AX
For further guidance,
please refer to HSE HSG53 "Respiratory Protective Equipment at work - A Practical Guide".
· Protection of hands:
· Material of gloves Not applicable.
· Penetration time of glove material Not applicable.
· Eye protection: Safety glasses (Contd. on page 4)
GB
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 31.07.2018 Revision: 17.07.2018Version number 15
Trade name: REINZOSIL (200 ml)
(Contd. of page 3)
47.0.4
· Body protection:
Protective work clothing
* SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Pasty
Colour: Anthracite
· Odour: Characteristic
· Melting point/freezing point: Undetermined.
· Initial boiling point and boiling range: Not applicable.
· Flash point: >151 °C
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product does not present an explosion hazard.
· Density at 20 °C: 1.07 g/cm³
· Solubility in / Miscibility with
water: Not miscible / difficult to mix.
· Solvent content:
VOC (EU) 0.4 g/l
VOC (EC) 0.04 %
· 9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity
· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products:
None if stored according to specifications.
Beginning at approx. 150 °C small amounts of formaldehyde are formed by an oxidative decomposition.
* SECTION 11: Toxicological information
· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
CAS: 58190-62-8 2-Pentanone, O,O',O''-(ethenylsilylidyne)trioxime
Oral LD50 1,000-2,000 mg/kg (rat)
· Primary irritant effect:
· Skin corrosion/irritation Slight irritation possible.
· Serious eye damage/irritation Slight irritation possible.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
(Contd. on page 5)
GB
Page 5/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 31.07.2018 Revision: 17.07.2018Version number 15
Trade name: REINZOSIL (200 ml)
(Contd. of page 4)
47.0.4
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
* SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
CAS: 58190-62-8 2-Pentanone, O,O',O''-(ethenylsilylidyne)trioxime
EC50/48 h >100 mg/L (daphnia magna)
· 12.2 Persistence and degradability No further relevant information available.
· Other information: The product is not biodegradable.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
· 13.1 Waste treatment methods
· Recommendation
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not
pierce or burn, even after use.
Cured product can be deposited together with domestic waste. Observe the specific related regulations
of local authorities.
· European waste catalogue
08 04 10 waste adhesives and sealants other than those mentioned in 08 04 09
16 05 05 gases in pressure containers other than those mentioned in 16 05 04
HP 3 Flammable
· Uncleaned packaging:
· Recommendation:
Empty packages totally (without drops or grains, cleaned with a spatula). Under observation of the
relevant local respectively national regulations re-use or recycling is preferred.
SECTION 14: Transport information
· 14.1 UN-Number
· ADR, IMDG, IATA UN1950
· 14.2 UN proper shipping name
· ADR 1950 DRUCKGASPACKUNGEN
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
(Contd. on page 6)
GB
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 31.07.2018 Revision: 17.07.2018Version number 15
Trade name: REINZOSIL (200 ml)
(Contd. of page 5)
47.0.4
· 14.3 Transport hazard class(es)
· ADR
· Class 2 5F Gases.
· Label 2.1
· IMDG, IATA
· Class 2.1
· Label 2.1
· 14.4 Packing group
· ADR, IMDG, IATA Void
· 14.5 Environmental hazards:
· Marine pollutant: No
· 14.6 Special precautions for user Warning: Gases.
· Danger code (Kemler): -
· EMS Number: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity of 1
litre: Category A. For AEROSOLS with a capacity
above 1 litre: Category B. For WASTE AEROSOLS:
Category C, Clear of living quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of 1
litre: Segregation as for class 9. Stow "separated
from" class 1 except for division 1.4. For AEROSOLS
with a capacity above 1 litre: Segregation as for the
appropriate subdivision of class 2. For W ASTE
AEROSOLS: Segregation as for the appropriate
subdivision of class 2.
· 14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· Transport category 2
· Tunnel restriction code D
· Remarks: - Special provisions: 190, 327, 344, 625 (3.3)
- Special provisions for carriage: V14 (7.2.4); CV9,
CV12 (7.5.11); S2 (8.5)
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· Remarks: - Special provisions: 63, 190, 277, 327, 344, 959 (3.3)
(Contd. on page 7)
GB
Page 7/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 31.07.2018 Revision: 17.07.2018Version number 15
Trade name: REINZOSIL (200 ml)
(Contd. of page 6)
47.0.4
· IATA
· Remarks: - Special provisions: A145, A167, A802 (4.4)
· UN "Model Regulation": UN 1950 AEROSOLS, 2.1
* SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
"CLP" Regulation (EC) No 1272/2008 (OJ L 353, 31.12.2008, p.1).
"REACH" Regulation (EC) No 1907/2006 (OJ L 396, 30.12.2006, p.1, with subsequent amendments).
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
75/324/EEC relating to aerosol dispensers
HSE EH40/2005 Workplace Exposure Limits (as amended)
· Directive 2012/18/EU
· Qualifying quantity (tonnes) for the application of lower-tier requirements 150 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3
· National regulations:
· Other regulations, limitations and prohibitive regulations
· Substances of very high concern (SVHC) according to REACH, Article 57 Not applicable.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
* SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H220 Extremely flammable gas.
H226 Flammable liquid and vapour.
H280 Contains gas under pressure; may explode if heated.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H412 Harmful to aquatic life with long lasting effects.
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
Flam. Gas 1: Flammable gases – Category 1
Aerosol 2: Aerosols – Category 2
Press. Gas (Comp.): Gases under pressure – Compressed gas
Flam. Liq. 3: Flammable liquids – Category 3
Acute Tox. 4: Acute toxicity – Category 4
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
· * Data compared to the previous version altered.
GB